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1 article(s) from Schillinger, Eva-Kathrin

Self-organizing bioinspired oligothiophene–oligopeptide hybrids

Alexey K. Shaytan,
Eva-Kathrin Schillinger,
Elena Mena-Osteritz,
Sylvia Schmid,
Pavel G. Khalatur,
Peter Bäuerle and
Alexei R. Khokhlov

Beilstein J. Nanotechnol. 2011, 2, 525–544, doi:10.3762/bjnano.2.57

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Figure 1: Various morphological organization examples of fibrillar aggregates that can be formed by polymer b...

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Scheme 1: Synthesis of quaterthiophene-β-sheet-peptide hybrid 1 [22]; (i) Hg(II)OAc₂, CHCl₃, 0 °C → r.t., 14 h; I₂...

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Scheme 2: Synthesis of quaterthiophene-β-sheet-peptide hybrid 6 [23]; (i) POCl₃, DMF, dichloroethane, reflux, 3 h...

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Figure 2: The A–B–A-type hybrid 1 in the deprotected, but still kinked, form 1'.

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Figure 3: AFM height images of hybrid 1' on mica from a 1:1 DCM/MeOH solution; a) left: Network of fibers aft...

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Figure 4: AFM images of the switched PEO–peptide–quaterthiophene–peptide–PEO compound 1 [22].

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Figure 5: A–B system 6' in deprotected, but still kinked, form.

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Figure 6: AFM height images of 6' on mica from a 1:1 DCM/MeOH solution. a) left: Image of fibers obtained aft...

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Figure 7: AFM height and amplitude images of fully switched PEO–peptide–quaterthiophene 6 on mica [23]. a) left: ...

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Figure 8: Calculated minimum energy conformation of oligothiophene–oligopeptide hybrid 1' in the three Cartes...

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Figure 9: a) Schematic representation of hybrid 1. Black coils: PEO chains, green arrow: Peptide strand; yell...

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Figure 10: Model for the self-assembly of hybrid 6', based on the theoretically calculated conformation of 6' ...

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Figure 11: Theoretical analysis workflow (see text).

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Figure 12: Constructed periodic crystalline cells for (a) antiparallel and (b) parallel arrangement of peptide...

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Figure 13: Possible options for the arrangement of β-sheets in a cross-β motif. Two identical sheets can be cl...

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Figure 14: Schematic representations of constructed double-layer periodic arrangements from the hybrid molecul...

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Figure 15: Snapshots of four different types of fibrils at the initial conformation (a1, b1, c1, d1) and after...

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Review

Published 05 Sep 2011

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